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i do not know about the safety of polyeurethane, but I do think its just NOT AS WATERPROOF as epoxy and if it has standing water on it for a long time that it will eventually break through the coating and crack and rot, no?

However, since you are doing a custom build, I wonder if you couldn't find some sort of plastic tray in the base of the viv to provide the additional waterproofing for the bottom?
 
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