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I would think that brass or copper would both be bad. One IS copper and the other is an alloy of Copper and Zinc. Zinc and Copper even in small amounts are toxic to many plants and animals and especially inverts. I don't know for certain that a tiny brass/copper nozzel on a mister head would introduce enough copper into a viv, even over the long term, but, with other alternatives available I wouldn't take the chance.
 
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